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Oxygen booster explosion: be careful!



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Old 22nd February 2008, 11:51   #41 (permalink)
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Re: Oxygen booster explosion: be careful!

Quote: (Originally Posted by Northern Monkey) View Original Post
I have used many of these one way valves myself, with no problems.

I spoke to Colin at Undersea and all the one way valves are supplied oxygen clean and he has never heard of any problems.

One suggestion is may be the one way valve may have been put into the system the wrong way round. Oxygen becomes unstable above 350 Bar.
I would imagine that the space between booster and valve is small and if in the wrong way any boosting would rapidly raise pressure and temperature.
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Old 24th February 2008, 19:28   #42 (permalink)
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Re: Oxygen booster explosion: be careful!

Quote: (Originally Posted by nigelh) View Original Post
I've heard this elsewhere but can anybody point me to same words?

All attempts at googling for it end up with me getting sidetracked into some fascinating stuff on astrophysics, super-conductors and para-magnetism but nothing on oxygen under pressure.

What does it do? Polymerise?
I read it in the instructions that came with my Haskel. Something like "Boosting oxygen above 346 bar is not recommended..." They never did explain why, just "don't do it, ok!"

What pressure does it become liquid at?
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Old 24th February 2008, 19:51   #43 (permalink)
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Re: Oxygen booster explosion: be careful!

Quote: (Originally Posted by Northern Monkey) View Original Post
Oxygen becomes unstable above 350 Bar.
Not exactly stable below 350 bar either........
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Old 24th February 2008, 19:55   #44 (permalink)
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Re: Oxygen booster explosion: be careful!

Quote: (Originally Posted by PeteS) View Original Post
What pressure does it become liquid at?
The boiling point will be a function of the pressure and temperature.

You aren't going to boost your way to a liquid state, you need very low temperatures also.

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Old 25th February 2008, 03:53   #45 (permalink)
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Re: Oxygen booster explosion: be careful!

What if you had access to liquid oxygen. Could you just pour that in to the tank?

If completely full with liquid how many bars would that rise up to when it reaches room temperature I wonder.
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Old 2nd April 2008, 09:51   #46 (permalink)
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Cool Re: Oxygen booster explosion: be careful!

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Old 2nd April 2008, 09:54   #47 (permalink)
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Old 2nd April 2008, 10:00   #48 (permalink)
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handling oxygen regardles,of any brand of booster pump is potentially dangerous.
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Old 2nd April 2008, 10:54   #49 (permalink)
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Re: Oxygen booster explosion: be careful!

Thank you for posting.

We have just used the video with our engineering team, as a reminder. Makes for good training material.

Iain supplied a nice little booster for 350bar O2 for bomb testing of O2 parts, so this is especially relevant as a reminder. It is besides us, as I post, and a the outside fire inspector is also here, wandering about our labs ...

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Old 4th April 2008, 14:47   #50 (permalink)
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Re: Oxygen booster explosion: be careful!

Quote: (Originally Posted by teomannaskali) View Original Post
What if you had access to liquid oxygen. Could you just pour that in to the tank?

If completely full with liquid how many bars would that rise up to when it reaches room temperature I wonder.
Ok this gets rather funky.

Liquid O2 expands something 850 times its volume at 1 bar, 15 Celsius). I got that from Air Liquide Gas Encyclopaedia.

But if you filled a vessle completely with LOX you would not get 850 bar when the gas has evaporated and the vessle has reached room temperature.

This is because the compressibility factor of the gas becomes very important at these pressures.

The charts I have are not so detailed but the closest compressibility value I have for O2 is: 1,66 at 1000 bar at 300 K (27 Celsius). That is also from Air Liquide Gas Encyclopaedia, but a printed more detailed version that I don't think is freely avalible online.

So if we do a very rough and probably rather incorrect guesstimate from the above compressibility factor and say that it is ~1,5 at 850 bar O2 for the same temp. That means that O2 at 850 bar and ~300 K only holds a factor of 1/1,5 as many moles of O2 as the ideal gas law would predict. Since we have a fixed number of moles in our case it implies that the pressure would have to be approximately that much higher (in our case).

So the pressure would be something like 850x1,5 = ~1275 bar!

Remember, the value is far from exact but the pressure should be something like that and definately higher than 850 bar.
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